New Approach to Making Graphene Could Lead to Workable Transistors

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Using DNA to synthesize and align ultra-thin graphene ribbons could represent a way to manufacture graphene transistors that don’t leak.

• By Mike Orcutt on September 12, 2013

Circuits made of graphene could be vastly more efficient and operate at much higher frequencies than those made of silicon.

Graphene growth: This image, taken using atomic force microscopy, shows graphene nanoribbons aligned in intersecting rows atop a silicon wafer. Researchers used DNA to synthesize and position the ribbons.

Researchers at Stanford have used DNA as a template to synthesize ultra-thin ribbons of graphene directly on silicon wafers. This new approach could ultimately lead to graphene transistors that leak less current and are thus more practical for electronics.
Graphene, a single-atom-thick carbon material first discovered in 2004, has electronic properties that make it attractive for use in integrated circuits. Electrons move much more quickly through graphene than silicon. But even the best graphene transistors are impractical for use in circuits because the material lacks a bandgap—a property of semiconductors that allows transistors to be switched on and off by changing the amount of current running through them. With graphene transistors, there’s too little difference between the amount of current running when they’re switched on versus when they’re off. This causes them to leak excessive amounts of current while in the off state.

Recent theoretical work and experimental evidence has suggested, however, that graphene ribbons less than 10 nanometers wide will exhibit a bandgap. But it’s very difficult to synthesize graphene structures of such dimensions and place them in the exact locations needed to be part of an electronic circuit. A group led by Zhenan Bao, a chemical engineering professor at Stanford, has now grown such graphene nanoribbons directly on silicon wafers.
To guide the placement and alignment of the ribbons, Bao used DNA. She and her colleagues spin-coated silicon substrates with a solution containing bundles of double-stranded DNA, the dimensions of which can be tuned by varying the composition of the buffer in the solution. The process results in thin DNA bundles as long as 20 micrometers aligned on the substrate. The researchers then infused the DNA with copper ions, and heated it at very high temperatures in the presence of methane gas and hydrogen. Graphene ribbons less than 10 nanometers wide formed from carbon that had comprised the DNA and methane, via a reaction catalyzed by the copper ions. (Bao notes that the ribbons aren’t perfect, and some regions have more than a single layer of carbon atoms, so they are more precisely called “graphitic.”) The research is described in a paper recently published in Nature Communications.
The group showed that the ribbons could be used in working transistors. Much about the method will need to improve if it is going to produce high-performing circuits. But the demonstration, says Bao, “opens up a new path” that could lead to a method for manufacturing graphene transistors and circuits at a large scale.
The approach is “very clever,” says James Tour, a chemistry professor at Rice University. Tour cautions that so-called bottom-up fabrication approaches like this one still have a long way to go to produce graphene structures precisely where they are needed. “For integration into large-scale systems, the traditional top-down approach is still hard to beat for alignment and placement,” he says.